The answer is all about Grub

Grub is the boot loader that Ubuntu has in it
Grub's role is to present the first black screen in order You to SELECT from which operating
system you may start (boot).Grub has also a buil in batch-like language and some options.you don't need a lot to know to change some options like boot order. You have to change the order of the titles in a file named menu.list. It is Just text but it is important so be careful , do not uncomment anything unless you know what you are doing
JUST change the order of the titles.

I will try to be more accurately*
So go to /boot/grub find a file called menu.lst open it with your favorite text editor and where is the titles for windows replace with linux titles all text about kernel and so on and where is linux bla bla bla replace with windows bla bla

1)I suggest you to make a back up of the file menu.lst in another directory like Desktop

2)If by mistake you make something bad the system will not boot SO then you must use a live cd to boot from cd/dvd and again open the menu.lst and correct it.

*BE AWARE Of making changes in it if you feel unsure or just ask somebody else

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